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Palladium recovery from acidic solution with phenanthroline-based covalent organic polymers as adsorbents for efficient heterogeneous catalysis

文献类型： 外文期刊

作者： Liu, Hui 1 ; Wu, Pengcheng 1 ; Wang, Ke 1 ; Li, Qing 2 ; Yu, Chengkan 1 ; Li, Xiaowei 1 ; Cai, Yimin 1 ; Feng, Wen 1 ; Yuan, Lihua 1 ;

作者机构： 1.Sichuan Univ, Coll Chem, Inst Nucl Sci & Technol, Key Lab Radiat Phys & Technol,Minist Educ, Chengdu 610064, Peoples R China

2.Sichuan Acad Agr Sci, Biotechnol & Nucl Technol Res Inst, Chengdu 610061, Peoples R China

期刊名称：GREEN CHEMISTRY （ 影响因子：9.8； 五年影响因子：9.8 ）

ISSN： 1463-9262

年卷期： 2024 年 26 卷 2 期

页码：

收录情况： SCI

摘要： The selective recovery and utilization of Pd(ii) from high-level liquid waste (HLLW) is highly desirable for both a flourishing circular economy and the sustainable development of nuclear energy. However, the design of suitable materials is an ongoing challenge due to the complicated composition and extremely radioactive and acidic conditions of HLLW, which requires exceptional selectivity and structural robustness of materials. In this study, two phenanthroline-based covalent organic polymers are constructed through polycondensation of 1,10-phenanthroline-2,9-dicarbaldehyde and 1,3,5-tris-(4-aminophenyl) triazine (COP-1) and subsequent oxidation of imine to amide groups (COP-2). COP-2 demonstrates a high adsorption capacity (318 mg g-1) and outstanding selectivity for Pd(ii) over 17 competing cations at 3 M HNO3 and is stable at high acidity (2-6 M HNO3) and under a strong radiation field of up to 600 kGy gamma irradiation. Additionally, COP-2 is reusable without an obvious decrease in adsorption efficiency after 5 cycles and is feasible for use in the dynamic column separation of Pd(ii). More importantly, the Pd(ii)-loaded COP-2 obtained from adsorption experiments can be employed as a highly efficient heterogeneous catalyst for Suzuki-Miyaura cross-coupling reactions with excellent reusability for more than 20 successive cycles. This work offers an example of turning wastes into wealth by rationally designing materials for precious metal recovery from HLLW and converting them into valuable catalysts. Highly efficient and selective recovery of Pd(II) from high-level liquid waste (HLLW) was realized by new phenanthroline-based organic polymers for subsequent heterogeneous catalysis of Suzuki-Miyaura cross-coupling reactions.

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