Bismuth-Decorated Honeycomb-like Carbon Nanofibers: An Active Electrocatalyst for the Construction of a Sensitive Nitrite Sensor
文献类型: 外文期刊
作者: Wang, Fengyi 1 ; Li, Ye 2 ; Yan, Chenglu 3 ; Ma, Qiuting 2 ; Yang, Xiaofeng 1 ; Peng, Huaqiao 3 ; Wang, Huiyong 4 ; Du, Juan 2 ; Zheng, Baozhan 2 ; Guo, Yong 2 ;
作者机构: 1.Sichuan Acad Agr Sci, Inst Qual Stand & Testing Technol Agroprod, Chengdu 610066, Peoples R China
2.Sichuan Univ, Coll Chem, 29 Wangjiang Rd, Chengdu 610064, Peoples R China
3.Second Res Inst Civil Aviat Adm China, Key Lab Aviat Fuel & Chem Airworthiness & Green De, Chengdu 610041, Peoples R China
4.Henan Normal Univ, Coll Chem & Chem Engn, Xinxiang 453002, Peoples R China
关键词: nitrite sensor; honeycomb-like carbon nanofibers; Bi nanoparticles; nitrite detection
期刊名称:MOLECULES ( 影响因子:4.6; 五年影响因子:4.9 )
ISSN:
年卷期: 2023 年 28 卷 9 期
页码:
收录情况: SCI
摘要: The existence of carcinogenic nitrites in food and the natural environment has attracted much attention. Therefore, it is still urgent and necessary to develop nitrite sensors with higher sensitivity and selectivity and expand their applications in daily life to protect human health and environmental safety. Herein, one-dimensional honeycomb-like carbon nanofibers (HCNFs) were synthesized with electrospun technology, and their specific structure enabled controlled growth and highly dispersed bismuth nanoparticles (Bi NPs) on their surface, which endowed the obtained Bi/HCNFs with excellent electrocatalytic activity towards nitrite oxidation. By modifying Bi/HCNFs on the screen-printed electrode, the constructed Bi/HCNFs electrode (Bi/HCNFs-SPE) can be used for nitrite detection in one drop of solution, and exhibits higher sensitivity (1269.9 mu A mM(-1) cm(-2)) in a wide range of 0.1 similar to 800 mu M with a lower detection limit (19 nM). Impressively, the Bi/HCNFs-SPE has been successfully used for nitrite detection in food and environment samples, and the satisfactory properties and recovery indicate its feasibility for further practical applications.
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