Analysis of oxovanadium(IV) complexes using electrospray mass spectrometry: Molecular ion formed by loss of an electron, and its product ions trapping oxygen
文献类型： 外文期刊
作者： Hou, Xue 2 ; Wu, Zhi-Jun 1 ; Zhao, Jian-Qiang 2 ; Yuan, Wei-Cheng 2 ; Qi, Hua-Yi 1 ;
作者机构： 1.Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Sichuan, Peoples R China
2.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China
3.Minist Agr, Lab Qual & Safety Risk Assessment Agroprod Chengd, Chengdu 610066, Sichuan, Peoples R China
期刊名称：RAPID COMMUNICATIONS IN MASS SPECTROMETRY （ 影响因子：2.419； 五年影响因子：2.439 ）
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收录情况： SCI
摘要： Rationale: In addition to their biological properties, oxovanadium complexes have been widely applied as catalysts because of their excellent catalytic-oxidation capability. Recently, monometallic oxovanadium(IV) complexes have been used as catalysts in the electrophilic trifluoromethylation of silyl ketene imines. The study of catalysts can contribute to an understanding of the reaction mechanism.
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